67556-29-0

Upstream product

• 293-42-5 heptathiazocine 
• 7647-18-9 antimonypentachloride 
• 67556-30-3 Cl₂BNS₇ 
• 1003-76-5 1,4-cyclodiazahexathiane 

Downstream Products

• 145854-71-3 {C₆H₅CNSNS}⁽¹⁺⁾*SbCl₆^(1-)={C₆H₅CNSNS}{SbCl₆} 
• 145854-73-5 {C₆F₅CNSNS}⁽¹⁺⁾*SbCl₆^(1-)={C₆F₅CNSNS}{SbCl₆} 

Relevant academic research and scientific papers

Preparation, vibrational spectra, and crystal structure of dithionitronium hexachloroantimonate(V), (S2N)(SbCl6)

Dithionitronium hexachloroantimonate(V), (S2N)(SbCl6), has been prepared by the reactions of S7NH, S7NBCl2, and 1,4-S6N2H2 with SbCl5 in liquid SO2. The structure of the compound has been determined by single-crystal X-ray diffraction. The orthorhombic crystal, space group I222, has cell dimensions a = 9.299 (3) ?, b = 7.976 (3) ?, and c = 7.070 (2) ? and has two formula units in the unit cell. Intensities were measured using Mo Ka radiation and a Syntex P21 diffractometer. The crystal structure was determined by standard methods and refined to R1 - 0.0377, R2 = 0.0375. The crystal is composed of linear S2N+ cations (N-S = 1.464 (3) ?) and approximately octahedral SbCl6- anions (Sb-Cl = 2.351 (3), 2.363 (2) ?). Infrared and Raman spectra of the solid compound are reported.