676165-04-1

Basic information

• Product Name: 2-Hexanone, 4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-5-methyl-, (4S)-
• CAS NO: 676165-04-1
• Molecular Formula: C23H32O2Si
• Molecular Weight: 368.591
• Mol File: 676165-04-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Hexanone, 4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-5-methyl-, (4S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexanone, 4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-5-methyl-, (4S)-(676165-04-1)
• EPA Substance Registry System: 2-Hexanone, 4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-5-methyl-, (4S)-(676165-04-1)

Safety Data

• Hazardous Substances Data: 676165-04-1(Hazardous Substances Data)

Upstream product

• 65651-63-0 4-hydroxy-5-methyl-hexan-2-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Relevant articles and documents

Studies on the Origin of 1,5-anti Induction in Boron-Mediated Aldol Reactions

A model for the origin of selectivity in boron-mediated 1,5-anti-aldols is presented. This model involves π-stacking between the boron enolate and a remote aromatic ring. A short, facile method for the synthesis of the C-12 to C-22 segment of peloruside A and its 1,5-anti-aldol coupling using the proposed model is also presented. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.