67617-36-1

Basic information

• Product Name: 2α-hydroxy-2,6,6-trimethybicyclo<3.1.1>heptan-3-one oxime
• Synonyms: 2α-hydroxy-2,6,6-trimethybicyclo<3.1.1>heptan-3-one oxime
• CAS NO: 67617-36-1
• Molecular Weight: 183.25
• Mol File: 67617-36-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2α-hydroxy-2,6,6-trimethybicyclo<3.1.1>heptan-3-one oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 2α-hydroxy-2,6,6-trimethybicyclo<3.1.1>heptan-3-one oxime(67617-36-1)
• EPA Substance Registry System: 2α-hydroxy-2,6,6-trimethybicyclo<3.1.1>heptan-3-one oxime(67617-36-1)

Safety Data

• Hazardous Substances Data: 67617-36-1(Hazardous Substances Data)

Upstream product

• 126004-00-0 (1S,2S,5S)-3-[(E)-(R)-Cyclohexyl-phenyl-methylimino]-2,6,6-trimethyl-bicyclo[3.1.1]heptan-2-ol 
• 126003-99-4 (1S,2S,5S)-3-[(E)-(R)-1,2-Diphenyl-ethylimino]-2,6,6-trimethyl-bicyclo[3.1.1]heptan-2-ol 
• 126003-98-3 (1S,2S,5S)-2,6,6-Trimethyl-3-[(E)-(R)-1-phenyl-ethylimino]-bicyclo[3.1.1]heptan-2-ol 
• 126003-99-4 (1R,2R,5R)-3-[(E)-(S)-1,2-Diphenyl-ethylimino]-2,6,6-trimethyl-bicyclo[3.1.1]heptan-2-ol 
• 126003-98-3 (1R,2R,5R)-3-[(1S)-α-methylbenzylimino]-2,6,6-trimethylbicyclo[3.1.1]heptan-2-ol 
• 126004-02-2 (1R,2R,5R)-3-[(E)-(S)-2-(3-Methoxy-phenyl)-1-phenyl-ethylimino]-2,6,6-trimethyl-bicyclo[3.1.1]heptan-2-ol 

Downstream Products

• 134101-92-1 8-(ethoxycarbonylacetylamino)-6-p-menthen-2-one oxime 
• 134101-88-5 8-acetylamino-p-menth-6-en-2-one oxime 
• 69363-09-3 (1S,2S,3R,5S)-3-amino-2,6,6-trimethylbicyclo[3.1.1]heptan-2-ol 
• 134101-90-9 8-N-(chloroacetyl)amino-p-menth-6-en-2-one oxime 
• 112091-01-7 8-hydroxy-6-p-menthen-2-one oxime 
• 134101-89-6 8-isobutyrylamino-p-menth-6-en-2-one oxime 
• 1845-25-6 (1S,2S,5S)-(-)-2-hydroxypinan-3-one 
• 7803-49-8 hydroxylamine 

Relevant articles and documents

ASYMMETRIC SYNTHESIS VIII: ENANTIONSELECTIVE SYNTHESIS OF (R) OR (S)-α-SUBSTITUTED BENZYLAMINES VIA CHIRAL PINANONE KETIMINE TEMPLATE

An excellent asymmetric synthesis of both (R) and (S)-α-substituted benzylamines in optical purity 90.4 - 99.9percent has been achieved by alkylation of a chiral ketimine, prepared from pinanone and benzylamine.Diastereoselectivity in the alkylation is not dependent on the alkyl halides.