67623-12-5Relevant academic research and scientific papers
Different structures modulated mechanochromism and aggregation-induced emission in a series of Gold(I) complexes
Wang, Xiao-Yan,Zhang, Jing,Dong, Yu-Bao,Zhang, Yiyue,Yin, Jun,Liu, Sheng Hua
, p. 74 - 81 (2018)
Five novel gold(I) complexes with various isocyanide ligands have been synthesized and characterized in present work. The introduction of different terminal ligands endows distinct diverse properties to complexes 1–5: i) alkyl modified complexes 1–3 exhibit tricolor or bicolor mechanochromic behaviors due to the loosing packing formed through weak intermolecular C–H···F interactions, while aryl bridged complexes 4 and 5 are not mechano-responsive with tight π-π stackings; ii) all the target complexes present prominent but different aggregation-induced emission(AIE) characteristics caused by the inherent difference in their structures. Therefore, the above gold(I) complexes are anticipated to be used as fluorescent detectors and mechanosensors.
