676241-01-3

Upstream product

• 108-24-7 acetic anhydride 
• 112219-66-6 (2R,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-2-(benzyloxymethyl)-6-vinyltetrahydro-2H-pyran 

Downstream Products

• 676241-03-5 ((2R,3R,4R,5S,6S)-3,4,5-Tris-benzyloxy-6-vinyl-tetrahydro-pyran-2-yl)-methanol 
• 676241-18-2 (2R,3R,4S,5R,6R)-6-{[((2R,3R,4S,5R,6R)-6-Azidomethyl-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carbonyl)-amino]-methyl}-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carboxylic acid tert-butyl ester 
• 676241-08-0 (2S,3S,4R,5S,6S)-6-{[((2S,3S,4R,5S,6S)-6-Azidomethyl-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carbonyl)-amino]-methyl}-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carboxylic acid tert-butyl ester 
• 676241-20-6 (2R,3R,4S,5R,6R)-6-{[((2R,3R,4S,5R,6R)-6-Aminomethyl-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carbonyl)-amino]-methyl}-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carboxylic acid tert-butyl ester 
• 676241-09-1 (2S,3S,4R,5S,6S)-6-{[((2S,3S,4R,5S,6S)-6-Aminomethyl-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carbonyl)-amino]-methyl}-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carboxylic acid tert-butyl ester 
• 676241-19-3 (2R,3R,4S,5R,6R)-6-{[((2R,3R,4S,5R,6R)-6-Azidomethyl-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carbonyl)-amino]-methyl}-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carboxylic acid 
• 676241-10-4 (2S,3S,4R,5S,6S)-6-{[((2S,3S,4R,5S,6S)-6-Azidomethyl-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carbonyl)-amino]-methyl}-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carboxylic acid 
• 676241-17-1 (2R,3R,4S,5R,6R)-6-Aminomethyl-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carboxylic acid tert-butyl ester 
• 676241-02-4 (2S,3S,4R,5S,6S)-6-Aminomethyl-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carboxylic acid tert-butyl ester 
• 676241-16-0 tert-butyl 2,6-anhydro-7-azido-3,4,5-tri-O-benzyl-7-deoxy-D-glycero-D-gulo-hepturonate 
• 676241-06-8 tert-butyl 2,6-anhydro-7-azido-3,4,5-tri-O-benzyl-7-deoxy-L-glycero-L-gluco-hepturonate 
• 676241-05-7 (2S,3S,4R,5S,6S)-3,4,5-Tris-benzyloxy-6-hydroxymethyl-tetrahydro-pyran-2-carboxylic acid tert-butyl ester 
• 676241-07-9 (2S,3S,4R,5S,6S)-6-Azidomethyl-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-carboxylic acid 
• 676241-04-6 (2S,3S,4R,5S,6S)-3,4,5-Tris-benzyloxy-6-vinyl-tetrahydro-pyran-2-carboxylic acid tert-butyl ester 

Relevant academic research and scientific papers

Synthesis of pyranoid δ-sugar amino acids and their oligomers from per-benzylated β-C-vinyl glucoside

Two pyranoid δ-sugar amino acids were prepared from the common per-benzylated β-C-vinyl glucoside and easily oligomerised using solution-phase coupling methodology.

Synthesis of several members of a new family of carbasugars: The cyclooctane mimetics

The TIBAL-promoted Claisen rearrangement of carbohydrates, developed in our group, has been applied to vinyl glycosides derived from D-glucose to afford highly functionalized cyclooctene derivatives in a stereospecific manner. Subsequent manipulation of these compounds gave access to a new family of carbasugars: the glucose and idose cyclooctanic mimetics.