676368-80-2

Basic information

• Product Name: [(η5-indenyl)Ru(PPh3)(4'-phenyl-2,2':6',2''-terpyridine)]PF6
• CAS NO: 676368-80-2
• Molecular Weight: 932.85
• Mol File: 676368-80-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(η5-indenyl)Ru(PPh3)(4'-phenyl-2,2':6',2''-terpyridine)]PF6(CAS DataBase Reference)
• NIST Chemistry Reference: [(η5-indenyl)Ru(PPh3)(4'-phenyl-2,2':6',2''-terpyridine)]PF6(676368-80-2)
• EPA Substance Registry System: [(η5-indenyl)Ru(PPh3)(4'-phenyl-2,2':6',2''-terpyridine)]PF6(676368-80-2)

Safety Data

• Hazardous Substances Data: 676368-80-2(Hazardous Substances Data)

Upstream product

• 58345-97-4 4'-phenyl-2,2':6',2-terpyridine 
• 241152-08-9 [(η5-indenyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate 

Relevant articles and documents

Reactions of [(Ar)Ru(PPh3)2(CH3CN)]X (Ar=Cp*, η5-C5Me5 and indenyl, η5-C9H7; X-PF6 o BF 4) with terpyridines: Hypodentate nature of terpyridines (phterpy, pyterpy and diterpy)

Ligand displacement reactions of the complexes of the type(Ar)Ru(PPh 3)2(CH3CN)]PF6 {Ar=Cp* (1) and indenyl (2)} have been investigated with N3-terpyridine ligands, 4′-phenyl-2,2′:6′,2″ terpyridine (phterpy), 4′-(4?-pyridyl)-2,2′:6′,2″ terpyridine (pyterpy) and 1,4-bis(2,2′:6,6″ terpyridin-4-yl) benzene (diterpy). The complexes [(Ar)Ru(PPh3)2(CH3CN)]PF6 {Ar=Cp* (1) and indenyl (2)} are reacted with these ligands to form stable complexes of the type [Cp*Ru(PPh3)(phterpy)]BF 4 (3), [Cp*Ru(PPh3)(pyterpy)]BF4 (4), [(η5ind)Ru(PPh3)(phterpy)]PF6 (5), [(η5ind)Ru(PPh3)(pyterpy)]PF6 (6), [(Cp*Ru(PPh3)}2 (diterpy)](BF4) 2 (7) and [(η5ind)Ru(PPh3)} 2(diterpy)l(PF6)2 (8) where respective ligands are coordinated in a bidentate fashion. When these reactions are carried out with chloro analogues [Cp*Ru(PPh3)2Cl] (9) and [(η5-ind)Ru(PPh3)2Cl] (10) with respective ligands viz. phterpy and pyterpy, a mixture of products are isolated including the complex type 3-6 and [RuCl(PPh3)2(N 3-phterpy)]PF6 (11) and [RuCl(PPh3) 2(N3-pyterpy)]PF6 (12) respectively. All these complexes have been characterized by spectral and analytical data.