67640-30-6Relevant academic research and scientific papers
Process for the preparation of halogenated benzoyl fluorides
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, (2008/06/13)
A process for the preparation of a halogenated benzoyl fluoride, which comprises contacting a halogenated benzotrifluoride of the formula STR1 in which m and n independently of one another represent an integer from 0 to 5, the sum of m and n being 5, with at least one sulphur compound of the formula STR2 in which X denotes fluorine, chlorine or hydroxyl and Y represents hydroxyl, or X and Y together denote an oxygen atom linked to the sulphur atom by a double bond, at an elevated temperature, and after reaction with the halogenated benzotrifluoride, removing the sulphur compound from the reaction mixture in the form of a compound of the formula STR3 in which X has the meaning given and Hal represents fluorine or chlorine, the reaction product is further reacted with potassium fluoride at an elevated temperature and under increased pressure.
