676466-70-9Relevant academic research and scientific papers
Suzuki-miyaura cross-coupling of potassium dioxolanylethyltrifluoroborate and aryl/heteroaryl chlorides
Fleury-Bregeot, Nicolas,Oehlrich, Daniel,Rombouts, Frederik,Molander, Gary A.
, p. 1536 - 1539 (2013/06/26)
A robust and efficient protocol for the introduction of the dioxolanylethyl moiety onto various aryl and heteroaryl halides has been developed, providing cross-coupling yields up to 93%. Copper-catalyzed borylation of 2-(2-bromoethyl)-1,3-dioxolane with bis(pinacolato)diboron followed by treatment with potassium bifluoride provides the key organotrifluoroborate reagent.
Nickel-catalyzed cross-coupling of alkyl zinc halides for the formation of C(sp2)-C(sp3) bonds: Scope and mechanism
Phapale, Vilas B.,Guisan-Ceinos, Manuel,Bunuel, Elena,Cardenas, Diego J.
supporting information; experimental part, p. 12681 - 12688 (2010/06/12)
Optimal conditions for a general Ni-catalysed Negishi cross-coupling of alkyl zinc halides with aryl, heteroaryl and alkenyl halides have been determined. These conditions allow the reaction to take place smoothly, with low catalyst loading, and in the pr
