676530-87-3

Upstream product

• 213997-99-0 phenyl 4,6-O-benzylidene-3-O-pivaloyl-1-thio-β-D-glucopyranoside 
• 289712-58-9 2-(azidomethyl)benzoyl chloride 

Downstream Products

• 676530-74-8 C₆₉H₉₃N₃O₁₂Si 
• 676530-88-4 10-[5-acetoxy-6-acetoxymethyl-3-(2-azidomethyl-benzoyloxy)-4-(2,2-dimethyl-propionyloxy)-tetrahydro-pyran-2-yloxy]-2,2,6a,6b,9,9,12a-heptamethyl-1,3,4,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-octadecahydro-2H-picene-4a-carboxylic acid 
• 676530-72-6 2-Azidomethyl-benzoic acid (3R,4S,5R,6R)-5-acetoxy-6-acetoxymethyl-4-(2,2-dimethyl-propionyloxy)-2-(2,2,2-trifluoro-N-phenyl-acetimidoyloxy)-tetrahydro-pyran-3-yl ester 
• 676530-71-5 2-Azidomethyl-benzoic acid (2S,3R,4S,5R,6R)-5-acetoxy-6-acetoxymethyl-4-(2,2-dimethyl-propionyloxy)-2-phenylsulfanyl-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Facile Synthesis of Ginsenoside Ro

Two concise synthetic routes, being different in the glycosylation sequence, toward ginsenoside Ro (1) are developed. These syntheses feature the elaboration of the glucuronide residue at a later stage via the TEMPO-mediated selective oxidation and the installation of AZMB as a benzoylic neighboring participating group capable of being selectively removed afterward.