676626-11-2Relevant academic research and scientific papers
Synthesis and catalytic activity of binuclear titanium imido complexes
Said, Musa,Hughes, David L.,Bochmann, Manfred
, p. 359 - 360 (2004)
Treatment of the N-P ligand ArPN(Si Me3)2 with TiCl4 affords the imido-bridged binuclear titanium complex [TiCl2(THF)(μ- NArP)]2 (ArP = m-C6H4 PR2) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of -PR2 functional groups.
