67698-90-2

Basic information

• Product Name: Benzene, 1,2-bis(hexyloxy)-4-methyl-
• CAS NO: 67698-90-2
• Molecular Formula: C19H32O2
• Molecular Weight: 292.462
• Mol File: 67698-90-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1,2-bis(hexyloxy)-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,2-bis(hexyloxy)-4-methyl-(67698-90-2)
• EPA Substance Registry System: Benzene, 1,2-bis(hexyloxy)-4-methyl-(67698-90-2)

Safety Data

• Hazardous Substances Data: 67698-90-2(Hazardous Substances Data)

Upstream product

• 111-25-1 1-bromo-hexane 
• 452-86-8 4-methyl-1,2-dihydroxybenzene 

Downstream Products

• 745825-51-8 3,4-di(n-hexyloxy)-6-methylthiophenol 

Relevant articles and documents

Substituted 5,6,11,12-tetradehydrodibenzo[ a, e ]cyclooctenes: Syntheses, properties, and DFT studies of substituted sondheimer-wong diynes

Highly strained cyclic acetylenes 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctenes (Sondheimer-Wong diynes) having various substituents on their benzene rings were synthesized successfully by one-pot treatment of the corresponding formyl sulfones with diethyl chlorophosphate/lithium hexamethyldisilazide (LiHMDS) and then lithium diisopropylamide (LDA). When mixtures of two types of formyl sulfones bearing different substituents were subjected to this protocol, the unsymmetrically substituted Sondheimer-Wong diynes could be synthesized in a stepwise manner by isolation of the heterocoupled vinyl sulfone intermediates followed by their treatment with LDA. The UV-vis absorption spectra and cyclic voltammograms of the substituted Sondheimer-Wong diynes were recorded. The electronic effect of substituents on the diynes was investigated in their click reactions and nucleophilic and electrophilic additions.