67728-84-1Relevant academic research and scientific papers
A NEW OXIGENATING METHOD USING 1-ALKOXYCARBONYL-1,2,4-TRIAZOLES AND HYDROGEN PEROXIDE RELATIVE REACTIVITY OF O-ALKYLPEROXYCARBONIC ACIDS
Tsunokawa, Youko,Iwasaki, Shigeo,Okuda, Shigenobu
, p. 4578 - 4581 (2007/10/02)
A convenient method is reported for the epoxidation of alkenes and the Baeyer-Villiger oxidation of a variety of carbonyl compounds using the 1-alkoxycarbonyl-1,2,4-triazoles (1a-c)/H2O2 system.The reactivities of the resulting peroxycarbonic acids were compared.O-Trichloroethylperoxycarbonic acid prepared in this way was isolated as a chloroform solution and was characterized spectroscopically.KEYWORDS - oxygenation with 1-alkoxycarbonyl-1,2,4-triazole/H2O2 system; peroxycarbonic acid; epoxidation; Baeyer-Villiger reaction
Novel prostaglandin intermediates
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, (2008/06/13)
The invention relates to (1α, 2α, 4α, 6α)-3-oxatricyclo[4.2.0.02,4 ]octane-7-one and derivatives thereof in which the ketone group is protected, which compounds are useful intermediates in the preparation of natural and synthetic prostaglandins. Processes for the preparation of these compounds are described and exemplified as are processes for their conversion into known prostaglandin intermediates.
