677343-52-1Relevant academic research and scientific papers
Metathesis-like splitting reactions of metallated [36]octaphyrins (1.1.1.1.1.1.1.1): Experimental and computational investigations
Tanaka, Yasuo,Shinokubo, Hiroshi,Yoshimura, Yosuke,Osuka, Atsuhiro
body text, p. 5674 - 5685 (2010/01/19)
meso-Octakis(pentafluoro-phenyl)-substituted [36]octaphyr-in(1.1.1.1.1.1.1. 1) (1) is a figure-of-eight nonaromatic macrocycle that serves as a unique platform to induce a metathesis-like splitting reaction upon bis-CuII metalation. To get a be
Metalation chemistry of meso-aryl-substituted expanded porphyrins
Shimizu, Soji,Osuka, Atsuhiro
, p. 1319 - 1335 (2007/10/03)
meso-Aryl-substituted expanded porphyrins are structural analogues of meso-aryl-substituted porphyrins. They exhibit rich and novel coordination behaviors, including multi-metal chelation due to the large cavities, spin-spin interaction arising from the proximity of metal centers, and large changes in their structural and electrochemical properties upon metalation. The recent discovery of a facile, one-pot synthesis of a series of meso-aryl-substituted expanded porphyrins enables us to investigate their metal-complexation chemistry. The aim of this Microreview is to highlight recent progress in the synthesis and characterization of metal complexes of meso-aryl-substituted expanded porphyrins. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
Thermal Splitting of Bis-Cu(II) Octaphyrin(1.1.1.1.1.1.1.1) into Two Cu(II) Porphyrins
Tanaka, Yasuo,Hoshino, Wataru,Shimizu, Soji,Youfu, Katsuyuki,Aratani, Naoki,Maruyama, Norihiko,Fujita, Shizuo,Osuka, Atsuhiro
, p. 3046 - 3047 (2007/10/03)
When heated, bis-Cu(II) octaphyrin(1.1.1.1.1.1.1.1) is quantitatively split into two Cu(II) porphyrins both in solution and film states, which is accompanied by large absorption spectral changes. Copyright
