677716-02-8

Basic information

• Product Name: (η1-2,6-(i-Pr)2C6H3NC(Me)CHC(Me)NC6H3(i-Pr)2-2,6)Ti(CN-t-Bu)(η2-(N,C)-t-BuNCCH2-t-Bu)(η2-(N,C)-t-BuNCPC6H2(t-Bu)3)
• CAS NO: 677716-02-8
• Molecular Weight: 1062.48
• Mol File: 677716-02-8.mol

Chemical Properties

• CAS DataBase Reference: (η1-2,6-(i-Pr)2C6H3NC(Me)CHC(Me)NC6H3(i-Pr)2-2,6)Ti(CN-t-Bu)(η2-(N,C)-t-BuNCCH2-t-Bu)(η2-(N,C)-t-BuNCPC6H2(t-Bu)3)(CAS DataBase Reference)
• NIST Chemistry Reference: (η1-2,6-(i-Pr)2C6H3NC(Me)CHC(Me)NC6H3(i-Pr)2-2,6)Ti(CN-t-Bu)(η2-(N,C)-t-BuNCCH2-t-Bu)(η2-(N,C)-t-BuNCPC6H2(t-Bu)3)(677716-02-8)
• EPA Substance Registry System: (η1-2,6-(i-Pr)2C6H3NC(Me)CHC(Me)NC6H3(i-Pr)2-2,6)Ti(CN-t-Bu)(η2-(N,C)-t-BuNCCH2-t-Bu)(η2-(N,C)-t-BuNCPC6H2(t-Bu)3)(677716-02-8)

Safety Data

• Hazardous Substances Data: 677716-02-8(Hazardous Substances Data)

Upstream product

• 606968-40-5 [Ti(CH₂CMe₃)(P(2,4,6-(C(CH₃)3)3C₆H₂)((2,6-(CH(CH₃)2)2C₆H₃)NC(Me)CHC(Me)N(2,6-(CH(CH₃)2)2C₆H₃))] 
• 119072-55-8 tert-butylisonitrile 

Relevant articles and documents

Phosphaazaallene and phosphinylimide complexes stemming from a terminal and four-coordinate titanium phosphinidene

Treatment of the terminal titanium-phosphinidene (Nacnac)Ti=PMes*(CH2tBu) (Nacnac- = [2,6-iPr2C6H3]- NC(CH3)CHC(CH3)N[2,6-iPr2 C6H3], Mes*- = 2,4,6-tBu3-C6H2) with CNtBu and N2CPh2, in pentane at -35°C, affords η2-(N,C)-phosphaazaallene and phosphinylimide complexes, respectively.