677764-27-1Relevant articles and documents
Ene cyclisations of α-(prenyl)dialkylsilyloxy aldehydes: Formation and oxidative cleavage of oxasilacyclohexanols
Robertson, Jeremy,Hall, Michael J.,Stafford, Petra M.,Green, Stuart P.
, p. 3758 - 3767 (2007/10/03)
A variety of routes are described for the synthesis of α-silyloxy aldehydes in which the silicon atom bears a prenyl side chain. These compounds are shown to undergo stereoselective carbonyl ene cyclisation under mildly Lewis acidic conditions and the der