677764-49-7

Upstream product

• 65733-49-5 (3-methyl-2-butenyl)triphenylstannane 
• 1631-83-0 diphenylsilyl chloride 
• 1829-58-9 (prop-2-enyl)diphenylsilane 
• 135582-87-5 (S)-methyl 3-(benzyloxycarbonylamino)-2-hydroxypropanoate 
• 677764-54-4 (S)-methyl N-(benzyloxycarbonyl)-O-[(3-methylbut-2-enyl)diphenylsilanyl]isoserinate 
• 370100-22-4 (3-methylbut-2-en-1-yl)diphenylsilane 

Downstream Products

• 677764-51-1 (3S,4R,5R)-3-{[(benzyloxycarbonyl)amino]methyl}-2-oxa-1,1-diphenyl-5-(propen-2-yl)silinan-4-ol 
• 866007-03-6 [(4S,5S)-5-(1,1-Dimethyl-allyl)-2,2-diphenyl-[1,3,2]dioxasilolan-4-ylmethyl]-carbamic acid benzyl ester 
• 866007-05-8 (2S,3S)-1-(benzyloxycarbonyl)amino-4,4-dimethylhex-5-en-2,3-diol 
• 1027199-55-8 (4S,5S)-5-[(benzyloxycarbonyl)amino]methyl-4-(1,1-dimethylprop-2-enyl)-1,3-dioxolane-2-thione 
• 866007-20-7 (2S,3S)-1-(benzyloxycarbonyl)amino-2,3-diacetoxy-4,4-dimethylhex-5-ene 

Relevant academic research and scientific papers

Silatropic carbonyl ene cyclizations in the synthesis of pseudosugars and hydroxylated piperidines

We describe two applications of silicon-tethered thermal allyl transfer reactions of α-silyloxyaldehydes; formally, these processes can be regarded as silatropic carbonyl ene reactions in which the silicon tether is transferred to the aldehyde oxygen conc

Ene cyclisations of α-(prenyl)dialkylsilyloxy aldehydes: Formation and oxidative cleavage of oxasilacyclohexanols

A variety of routes are described for the synthesis of α-silyloxy aldehydes in which the silicon atom bears a prenyl side chain. These compounds are shown to undergo stereoselective carbonyl ene cyclisation under mildly Lewis acidic conditions and the der