67809-14-7

Basic information

• Product Name: NITROSOMETHYLFORMAMIDE
• Synonyms: NITROSOMETHYLFORMAMIDE
• CAS NO: 67809-14-7
• Molecular Formula: C2H4N2O2
• Molecular Weight: 88.0654
• Mol File: 67809-14-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 94.9°Cat760mmHg
• Flash Point: 11.2°C
• Appearance: /
• Density: 1.2g/cm³
• Vapor Pressure: 46.5mmHg at 25°C
• Refractive Index: 1.465
• CAS DataBase Reference: NITROSOMETHYLFORMAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: NITROSOMETHYLFORMAMIDE(67809-14-7)
• EPA Substance Registry System: NITROSOMETHYLFORMAMIDE(67809-14-7)

Safety Data

• Hazardous Substances Data: 67809-14-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C2H4N2O2/c1-4(2-5)3-6/h2H,1H3

Upstream product

• 123-39-7 N-Methylformamide 

Relevant articles and documents

Bismuth chloride-sodium nitrite: A novel reagent for chemoselective N-nitrosation

Bismuth(III) chloride-sodium nitrite was used as a mild and efficient reagent for N-nitrosation of various tetrazoles, secondary amines, and amides under ambient conditions. Nitrosation took place chemoselectively at the nitrogen atom, giving corresponding N-nitroso derivatives in good to excellent yield. Copyright Taylor & Francis Group, LLC.

Selective N-nitrosation of amines, N-alkylamides and N-alkylureas by N2O4 supported on cross-linked polyvinylpyrrolidone (PVP-N2O4)

N2O4 was supported on the cross-linked polyvinylpyrrolidone (PVP) to afford a solid, stable and recyclable nitrosating agent. This reagent shows excellent selectivity for N-nitrosation of dialkyl amines in the presence of diaryl-, arylalkyl-, trialkylamines and also for secondary amides in dichloromethane at room temperature under mild and heterogeneous conditions. Also N-nitroso-N-alkyl amides can be selectively prepared in the presence of primary amides and N-phenylamides under similar reaction conditions. Selective N-nitrosation or dealkylation and N-nitrosation of tertiary amines can also be performed by this reagent.