67810-92-8

Basic information

• Product Name: 2-(o-Tolyl)-1,3-dithiolane
• Synonyms: 2-(o-Tolyl)-1,3-dithiolane
• CAS NO: 67810-92-8
• Molecular Formula: C₁₀H₁₂S₂
• Molecular Weight: 196.3323
• Mol File: 67810-92-8.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 326.2°Cat760mmHg
• Flash Point: 157.8°C
• Appearance: /
• Density: 1.167g/cm³
• Vapor Pressure: 0.000416mmHg at 25°C
• Refractive Index: 1.624
• CAS DataBase Reference: 2-(o-Tolyl)-1,3-dithiolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(o-Tolyl)-1,3-dithiolane(67810-92-8)
• EPA Substance Registry System: 2-(o-Tolyl)-1,3-dithiolane(67810-92-8)

Safety Data

• Hazardous Substances Data: 67810-92-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H12S2/c1-8-4-2-3-5-9(8)10-11-6-7-12-10/h2-5,10H,6-7H2,1H3

Upstream product

• 118-90-1 ortho-methylbenzoic acid 
• 540-63-6 ethane-1,2-dithiol 
• 5469-00-1 2-(Diethoxymethyl)methylbenzene 
• 529-20-4 2-methylphenyl aldehyde 

Downstream Products

• 529-20-4 2-methylphenyl aldehyde 
• 113509-23-2 (E)-1-methyl-2-(2-trimethylsilylethenyl)benzene 

Relevant articles and documents

Visible-Light Photoredox-Catalyzed Thioacetalization of Aldehydes Under Metal-Free and Solvent-Free Conditions

A first visible-light photoredox-catalyzed thioacetalization of aldehydes under metal-free and solvent-free conditions is described. Under blue LED irradiation, a reactive thiyl radical was initially generated through single-electron oxidation of thiol, w

One-pot two-step conversion of aromatic carboxylic acids and esters to aromatic aldehydes via indium-catalyzed reductive thioacetalization and desulfurization

Described herein is that a new approach to a one-pot two-step conversion of aromatic carboxylic acids/esters to aromatic aldehydes, in which indium(III) iodide effectively catalyzes both the first reductive thioacetalization of carboxylic acids and a subsequent desulfurization of the in-situ formed thioacetal intermediates leading to aldehydes.

Aluminum hydrogen sulfate [Al(HSO4)3] as an efficient catalyst for the preparation of thioacetals

Aluminum hydrogen sulfate, as a heterogeneous solid acid catalyst, has been used for the mild conversion of carbonyl compounds to their thioacetals using 1,2- and 1,3-dithiol under ambient conditions with short reaction times in high to excellent yield in