67814-35-1

Upstream product

• 23963-16-8 (1S,3S,4R)-3-hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 77078-77-4 (1R,2S,4S)-2-exo-(Trimethylsilyloxy)-3-bornanon 
• 591-51-5 phenyllithium 

Downstream Products

• 1314357-64-6 (1R,2S,3S,4S)-4-iodomethyl-1,10,10-trimethyl-3-phenyl-3,5-dioxa-4-boratricyclo[5.2.1.0^0,0]decane 
• 67760-74-1 (-)-(1R,2S,3S,4S)-2,3-O-Allylborylen-3-endo-phenyl-2-exo,3-exo-bornandiol 
• 72985-58-1 (-)-(1R,2S,3S,4S)-exo-2-exo-3-<(Z)-2-butenylborylenedioxy>-endo-3-phenylbornane 

Relevant academic research and scientific papers

Stereoselektive Synthese von Alkoholen, VI. Asymmetrische Synthesen von 4-Penten-2-ol ueber Allylboronsaeureester chiraler Glycole

Allylboronates 3 of substituted camphor glycols 2 add to acetaldehyde giving 4-penten-2-ol (1).The substituents affect the extent of asymmetric induction in an additive manner.Pentenol of 86percent enantiomeric purity was obtained using 2d as chiral matrix.