678144-55-3Relevant academic research and scientific papers
Catalytic Regiodivergent Kinetic Resolution of Allylic Epoxides: A New Entry to Allylic and Homoallylic Alcohols with High Optical Purity
Pineschi, Mauro,Del Moro, Federica,Crotti, Paolo,Di Bussolo, Valeria,Macchia, Franco
, p. 2099 - 2105 (2007/10/03)
A novel regiodivergent kinetic resolution of a series of allylic epoxides with alkylzinc reagents is described. Results demonstrate the potential of chiral copper-phosphoramidite catalysts for enantiomer differentiation of allylic epoxides, allowing a chiral catalyst-stereoregulated synthesis of cyclic allylic and homoallylic alcohols with high optical purities.
