678166-21-7Relevant academic research and scientific papers
Sterically congested chiral activated aziridines: Synthesis of both 2,3- cis-and 2,3-Trans-2-alkenyl-3-alkylaziridines from common intermediates
Ohno,Toda,Fujii,Miwa,Taga,Yamaoka,Osawa,Ibuka
, p. 1331 - 1334 (1999)
Whereas treatment of the allylic mesylates of N-protected 2-alkyl-4- amino-(E)-2-alken-1-ols with sodium hydride in DMF yields exclusively the corresponding 2,3-trans-2-alkenyl-3-alkylaziridines, exposure of the methyl carbonates of N-protected 2-alkyl-4-
Stereodivergent synthesis of chiral 2-alkenylaziridines: Palladium(0)-catalyzed 2,3-cis-selective aziridination and base-mediated 2,3-trans-selective aziridination
Ohno, Hiroaki,Takemoto, Yoshiji,Fujii, Nobutaka,Tanaka, Tetsuaki,Ibukab, Toshiro
, p. 111 - 119 (2007/10/03)
Whereas treatment of the allylic mesylates of N-protected 2-alkyl-4-amino-(E)-2-alken-1-ols with sodium hydride in DMF yields exclusively the corresponding thermodynamically less stable 2,3-trans-2-alkenyl-3- alkylaziridines, exposure of the methyl carbon
