678166-34-2

Upstream product

• 678166-28-4 methyl (4S,5S,2E)-2,5-dimethyl-4-[N-(2,4,6-trimethylphenylsulfonyl)amino]hept-2-enoate 
• 678166-22-8 (2S,3S)-N-(2,4,6-trimethylbenzenesulfonyl)-2-amino-3-methyl-pentanol 
• 24629-25-2 (S)-isoleucinol 
• 773-64-8 2-mesitylenesulphonyl chloride 

Downstream Products

• 221278-60-0 (4S,5S,2E)-O-methoxycarbonyl-2,5-dimethyl-4-[N-(2,4,6-trimethylphenylsulfonyl)amino]hept-2-en-1-ol 
• 221278-70-2 (4S,5S,2E)-2,5-dimethyl-4-[N-(2,4,6-trimethylphenylsulfonyl)amino]-O-methylsulfonylhept-2-en-1-ol 

Relevant academic research and scientific papers

Stereodivergent synthesis of chiral 2-alkenylaziridines: Palladium(0)-catalyzed 2,3-cis-selective aziridination and base-mediated 2,3-trans-selective aziridination

Whereas treatment of the allylic mesylates of N-protected 2-alkyl-4-amino-(E)-2-alken-1-ols with sodium hydride in DMF yields exclusively the corresponding thermodynamically less stable 2,3-trans-2-alkenyl-3- alkylaziridines, exposure of the methyl carbon