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16,28-Secosolanid-5-ene-3,16-diol, (3beta,16beta,22alpha,25beta)- is a complex steroidal compound characterized by its unique molecular structure. It is a derivative of the secosterol family, which are steroids that have undergone a ring cleavage, resulting in a reduced structure. This particular compound features a 5-ene double bond and two hydroxyl groups at the 3 and 16 positions, with the stereochemistry specified by the prefixes beta and alpha, indicating the spatial arrangement of these functional groups. The compound's structure is further defined by the presence of a 22alpha and 25beta configuration, which are crucial for its biological activity and potential applications. This chemical is of interest in the field of organic chemistry and may have implications in pharmaceutical research due to its structural similarity to natural steroids, which are known for their diverse biological effects.

6785-55-3

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6785-55-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 6785-55-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,7,8 and 5 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 6785-55:
(6*6)+(5*7)+(4*8)+(3*5)+(2*5)+(1*5)=133
133 % 10 = 3
So 6785-55-3 is a valid CAS Registry Number.
InChI:InChI=1/C27H45NO2/c1-16-5-8-23(28-15-16)17(2)25-24(30)14-22-20-7-6-18-13-19(29)9-11-26(18,3)21(20)10-12-27(22,25)4/h6,16-17,19-25,28-30H,5,7-15H2,1-4H3/t16-,17-,19+,20-,21+,22+,23-,24+,25?,26+,27+/m1/s1

6785-55-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (22S,25R)-22,26-epiminocholest-5-ene-3β,16β-diol

1.2 Other means of identification

Product number -
Other names (22S,25R)-16,28-seco-solanid-5-ene-3β,16β-diol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6785-55-3 SDS

6785-55-3Relevant academic research and scientific papers

TWO STEROIDAL ALKALOIDS, HAPEPUNINE AND ANRAKORININE, FROM THE MATURE FRITILLARIA CAMTSCHATCENSIS

Kaneko,Ko,Nakaoka, Utako,Tanaka, Mikako,Yoshida, Naotoshi,Mitsuhashi, Hiroshi

, p. 157 - 160 (1981)

Key word Index - Fritillaria camtschatcensis; Liliaceae; N-methyl-22,26-epiminocholestene; spirosolane. After acid hydrolysis of a glycosidic fraction from aerial parts of Fritillaria camtschatcensis, in addition to solanidine, tomatidenol, and solasodine, two N-methyl-22,26-epiminocholestenes, hapepunine and anrakorinine, were isolated and their structures elucidated by physical and chemical methods.

Solanum Alkaloids, 124, Preparation of N-Hydroxyspirosolane Alkaloids

Ripperger, Helmut

, p. 1091 - 1094 (2007/10/02)

The N-Hydroxyspirosolane alkaloids N-hydroxysolasodine (1) and N-hydroxytomatidine (10) as well as the N-hydroxy-22,26-epiminocholestene 7 have been prepared by oxidation of the respective amines 2, 11, and 5 with hydrogen peroxide in the presence of selenium dioxide.Key Words: Solasodines / Tomatidines / Alkaloids / Solanum steroid alkaloids / Spirosolanes / Steroids

Partial Synthesis of the Steroid Alkaloids Teinemine, 22-Isoteinemine, Etioline, and 25-Isoetioline

Quyen, Le thi,Ripperger, Helmut,Schreiber, Klaus

, p. 143 - 149 (2007/10/02)

The rare 16α-hydroxylated steroid alkaloids teinemine , 22-isoteinemine , etioline , and 25-isoetioline are synthesized from the abundant spirosolane alkaloids tomatid-5-en-3β-ol and solasodine , respectively.The crucial stages of these syntheses are the conversion of 1 or 15 into the N-protected (22S,25S)-, (22R,25S)-, and (22S,25R) -22,26-epimino-3β-hydroxycholest-5-en-16-ones 6, 7, and 18 as well as their reductions with sodium/2-propanol to the 16α-hydroxy compounds teinemine (8), 22-isoteinemine (10), and (22S,25R)-22,26-epiminocholest-5-ene-3β,16α-diol (19), respectively.By treatment with sodium methanolate the N-chloro derivatives 9 and 11 of 8 and 10 afford etioline (12).In an analogous manner, the N-chloro derivative 20 of 19 is converted into 25-isoetioline (21).

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