67873-26-1

Basic information

• Product Name: Octanoic acid, 2-oxo-, ethyl ester
• CAS NO: 67873-26-1
• Molecular Formula: C10H18O3
• Molecular Weight: 186.251
• Mol File: 67873-26-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Octanoic acid, 2-oxo-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Octanoic acid, 2-oxo-, ethyl ester(67873-26-1)
• EPA Substance Registry System: Octanoic acid, 2-oxo-, ethyl ester(67873-26-1)

Safety Data

• Hazardous Substances Data: 67873-26-1(Hazardous Substances Data)

Upstream product

• 1418125-10-6 ethyl 2-(4-methoxybenzoyl)octanoate 
• 1418125-41-3 ethyl 2-(4-methylbenzoyl)octanoate 
• 118067-03-1 2-benzoyloctanoic acid ethyl ester 
• 1418125-40-2 ethyl 2-(4-chlorobenzoyl)octanoate 

Downstream Products

• 1204769-88-9 4-benzyl 1-ethyl 2-hexyl-2-hydroxybutanedioate 
• 1024608-43-2 3-hydroxy-1-(3-imidazol-1-yl-propyl)-5-(4-methoxy-phenyl)-4-pentyl-1,5-dihydro-pyrrol-2-one 
• 1024608-69-2 3-hydroxy-5-(3-hydroxy-phenyl)-1-(3-imidazol-1-yl-propyl)-4-pentyl-1,5-dihydro-pyrrol-2-one 
• 1024608-68-1 3-hydroxy-5-(4-hydroxy-phenyl)-1-(3-imidazol-1-yl-propyl)-4-pentyl-1,5-dihydro-pyrrol-2-one 
• 1024608-66-9 5-(3-chloro-phenyl)-3-hydroxy-1-(3-imidazol-1-yl-propyl)-4-pentyl-1,5-dihydro-pyrrol-2-one 
• 1024608-67-0 5-(2-fluoro-phenyl)-3-hydroxy-1-(3-imidazol-1-yl-propyl)-4-pentyl-1,5-dihydro-pyrrol-2-one 
• 111935-01-4 octanoic acid, (+/-)-5,5-difluoro-4-oxo-2-<<oxy>methyl>undecyl ester 
• 1117-86-8 (R)-1,2-octanediol 
• 1117-86-8 1,2-octandiol 
• 188530-98-5 ethyl 3-[(p-nitrobenzenesulfonyl)oxy]-2-oxooctanoate 
• 200286-62-0 (E)-2-(1-Phenylselanyl-hexyl)-but-2-enedioic acid diethyl ester 

Relevant articles and documents

Mechanism and scope of the MnIII-initiated oxidation of β-ketocarbonyl compounds: Furan synthesis

Unless the MnIII-produced carbon-radical from β-ketocarbonyl compounds undergoes smooth intramolecular addition to alkenes, it traps molecular oxygen in the reaction medium to produce a peroxy radical, which reacts with the neighbouring carbonyl group to form 1,2-dioxetane. Thermal decomposition of 1,2-dioxetane completes the oxidation to produce α-oxo ester. This oxidation seems to be general at 50°C under aerobic conditions, and can be catalytic for MnIII in AcOH with ultrasonic irradiation. Thus, the development of a new synthetic method for diversely substituted furans has been accomplished based on a couple of the MnIII-initiated domino oxidation of β-ketocarbonyl compounds with a suitable α-allylic substitution. Copyright