67888-34-0 Usage
Uses
Used in Organic Synthesis:
8-bromocinnoline is used as a building block in the synthesis of various pharmaceuticals and functional materials, contributing to the development of new compounds with potential therapeutic and practical applications.
Used in Materials Science:
In the field of materials science, 8-bromocinnoline is utilized for its favorable electronic properties, making it a key component in the creation of advanced materials with specific functionalities.
Used in Organic Light-Emitting Diodes (OLEDs):
8-bromocinnoline is employed as a component in the development of OLEDs, where its electronic properties are leveraged to enhance the performance and efficiency of these light-emitting devices.
Used in Organic Photovoltaic Devices:
8-bromocinnoline also finds application in the realm of organic photovoltaics, where it contributes to the improvement of solar cell technologies by optimizing the conversion of light into electricity.
Used as a Fluorescent Probe in Analytical Chemistry:
8-bromocinnoline has demonstrated its potential as a fluorescent probe for the detection of metal ions, offering a sensitive and selective method for analytical applications in chemistry.
Used as a Photocatalyst in Organic Transformations:
Furthermore, 8-bromocinnoline serves as an efficient photocatalyst in various organic transformations, facilitating chemical reactions under the influence of light, which is valuable for the synthesis of complex organic molecules.
Check Digit Verification of cas no
The CAS Registry Mumber 67888-34-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,7,8,8 and 8 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 67888-34:
(7*6)+(6*7)+(5*8)+(4*8)+(3*8)+(2*3)+(1*4)=190
190 % 10 = 0
So 67888-34-0 is a valid CAS Registry Number.
InChI:InChI=1/C8H5BrN2/c9-7-3-1-2-6-4-5-10-11-8(6)7/h1-5H
67888-34-0Relevant academic research and scientific papers
TMP-magnesium and TMP-Zinc bases for the regioselective metalation of the cinnoline scaffold
Klatt, Thomas,Roman, Daniela Sustac,Leon, Thierry,Knochel, Paul
supporting information, p. 1232 - 1235 (2014/03/21)
A regioselective functionalization of cinnolines in positions 3 and 8 using metalations has been developed. This involves either the use of a frustrated Lewis pair consisting of BF3·Et2O and TMP 2Mg·2LiCl or the in situ generated base TMP 2Zn·2MgCl2·2LiCl. Successive metalations allow the preparation of 3,8-disubstituted cinnolines. Various functionalizations by acylation, allylation, and cross-coupling reactions with aryl halides or alkenyl iodides were carried out successfully.