67904-66-9Relevant academic research and scientific papers
Cobalt(III)-Catalyzed Intermolecular Carboamination of Propiolates and Bicyclic Alkenes via Non-Annulative Redox-Neutral Coupling
Zhu, Yuelu,Chen, Feng,Zhao, Xinyang,Yan, Dingyuan,Yong, Wanxiong,Zhao, Jing
, p. 5884 - 5888 (2019)
A cobalt(III)-catalyzed, redox-neutral, intermolecular carboamination of propiolates and bicyclic alkenes was developed. This non-annulative coupling strategy features atom economy, high regioselectivity, good yields, and functional groups tolerance. Such a carboamination reaction was applied to modified phenols from the corresponding phenols under mild conditions.
Fully substituted pyranones via quasi-heterogeneous genuinely ligand-free migita-stille coupling of iodoacrylates
Kratochv??l, Ji????,Nov??k, Zden??k,Ghavre, Mukund,Nov??kov??, Lucie,R????i??ka, Ale??,Kune??, Ji????,Pour, Milan
supporting information, p. 520 - 523 (2015/03/04)
Migita-Stille coupling of (Z)-?2-iodoacrylates with (E)-?±-stannyl allylic alcohols to furnish 5-alkylidene-4-substituted-5,6-dihydro-2H-pyran-2-ones is efficiently catalyzed by 2% Pd black in DMF, while Pd(PPh3)4 is inactive. Heterogeneous Pd released in solution is most likely responsible for the catalysis. The reaction is applicable to other substrates, without having to resort to ligands, additives, and/or solid support for Pd. The resulting pyranones can be rearranged to fully functionalized pyranones in another single step.
Synthesis and rearrangement of dewar benzenes into biaryls: Experimental evidence for conrotatory ring opening
Jankova, Stepanka,Dracinsky, Martin,Cisarova, Ivana,Kotora, Martin
, p. 47 - 51 (2008/09/17)
Rearrangement of aryl-substituted Dewar benzenes into the corresponding biaryls may serve as an alternative pathway for synthesis of sterically hindered biaryls. The kinetic data obtained from thermal rearrangements of Dewar benzenes provide experimental
