679411-88-2

Upstream product

• 623157-43-7 (2S,6S)-carbonic acid tert-butyl ester 6-(tert-butyl-dimethyl-silanyloxymethyl)-4-oxo-2,3-dihydro-6H-pyran-2-yl ester 
• 302348-82-9 (2S)-2-(((tert-butyldimethylsilyl)oxy)methyl)-6-hydroxy-2H-pyran-3(6H)-one 
• 222986-37-0 (S)-2-((tert-butyldimethylsilyl)oxy)-1-(furan-2-yl)ethan-1-ol 
• 623157-48-2 (2S,6R)-6-(benzyloxy)-2-(((tert-butyldimethylsilyl)oxy)methyl)-2H-pyran-3(6H)-one 

Downstream Products

• 679411-89-3 (1'R,5'S,1R,5S)-1-[1'-benzyloxy-5'-methyloxy-1'H-pyran-4'-one]-5-(tert-butyldimethylsilanyloxymethyl)-1H-pyran-4-one 
• 679411-94-0 (1''R,4''R,5''S,1'R,4'R,5'S,1R,4R,5S)-1-[1'-[1''-benzyloxy-5''-methyloxy-1''H-pyran-4''-ol]-5'-methyloxy-1'H-pyran-4'-ol]-5-(tert-butyldimethylsilanyloxymethyl)-1H-pyran-4-ol 
• 679411-91-7 (1''R,5''S,1'R,5'S,1R,5S)-1-[1'-[1''-benzyloxy-5''-methyloxy-1''H-pyran-4''-one]-5'-methyloxy-1'H-pyran-4'-one]-5-(tert-butyldimethylsilanyloxymethyl)-1H-pyran-4-one 
• 679411-92-8 (1'R,5'S,1R,5S)-1-[1'-benzyloxy-5'-methyloxy-1'H-pyran-4'-ol]-5-(tert-butyldimethylsilanyloxymethyl)-1H-pyran-4-ol 
• 679411-90-6 (1'R,5'S,1R,5S)-1-[1'-benzyloxy-5'-methyloxy-1'H-pyran-4'-one]-5-hydroxymethyl-1H-pyran-4-one 

Relevant academic research and scientific papers

De Novo Synthesis of Oligosaccharades Using a Palladium-Catalyzed Glycosylation Reaction

The natural all d- and/or unnatural all l-1,4- and 1,6-oligosaccharides were synthesized from furan alcohols using a palladium-catalyzed glycosylation reaction. The 1,4- and 1,6-α-manno-disaccharides were achieved in seven total steps starting from chiral furan alcohols. Similarly, 1,4- and 1,6-α-manno-trisaccharides were also synthesized in nine total steps. Key to the overall efficiency of this process was the use of highly diastereoselective palladium-catalyzed glycosylations, reductions, and dihydroxylations. Copyright