679411-97-3

Upstream product

• 623157-49-3 (2S,3R,6R)-6-(benzyloxy)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3,6-dihydro-2H-pyran-3-ol 
• 623157-48-2 (2S,6R)-6-(benzyloxy)-2-(((tert-butyldimethylsilyl)oxy)methyl)-2H-pyran-3(6H)-one 
• 302348-82-9 (2S)-2-(((tert-butyldimethylsilyl)oxy)methyl)-6-hydroxy-2H-pyran-3(6H)-one 
• 222986-37-0 (S)-2-((tert-butyldimethylsilyl)oxy)-1-(furan-2-yl)ethan-1-ol 
• 679411-96-2 (1'R,4'R,5'S,1R,5S)-1-[1'-benzyloxy-5-(tert-butyldimethylsilanyloxymethyl)-1',4'-dihydro-5'H-pyran-4'-yloxy]-5-(tert-butyldimethylsilanyloxymethyl)-1H-pyran-4-one 

Downstream Products

• 679411-98-4 6-[6-[6-benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-yloxy]-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-yloxy]-2-(tert-butyl-dimethyl-silanyloxymethyl)-6H-pyran-3-one 
• 679412-00-1 6-[6-[6-benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-yloxy]-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-yloxy]-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-ol 

Relevant academic research and scientific papers

De Novo Synthesis of Oligosaccharades Using a Palladium-Catalyzed Glycosylation Reaction

The natural all d- and/or unnatural all l-1,4- and 1,6-oligosaccharides were synthesized from furan alcohols using a palladium-catalyzed glycosylation reaction. The 1,4- and 1,6-α-manno-disaccharides were achieved in seven total steps starting from chiral furan alcohols. Similarly, 1,4- and 1,6-α-manno-trisaccharides were also synthesized in nine total steps. Key to the overall efficiency of this process was the use of highly diastereoselective palladium-catalyzed glycosylations, reductions, and dihydroxylations. Copyright