67951-97-7

Basic information

• Product Name: 2-(Diphenylmethylen)-1,3-dithiolan
• CAS NO: 67951-97-7
• Molecular Weight: 270.419
• Mol File: 67951-97-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(Diphenylmethylen)-1,3-dithiolan(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Diphenylmethylen)-1,3-dithiolan(67951-97-7)
• EPA Substance Registry System: 2-(Diphenylmethylen)-1,3-dithiolan(67951-97-7)

Safety Data

• Hazardous Substances Data: 67951-97-7(Hazardous Substances Data)

Upstream product

• 117-34-0 2,2-diphenylacetic acid 
• 540-63-6 ethane-1,2-dithiol 

Downstream Products

• 102861-90-5 2-(Diphenylmethylen)-1-ethyl-1,3-dithiolanium-tetrafluoroborat 
• 113354-20-4 2-(Diphenylmethylen)-1,3-dithiolan-1-oxid 
• 113354-29-3 <1-(Methylthio)-2,2-diphenylvinyl>vinylsulfon 
• 113354-09-9 2-(Diphenylmethylen)-1,3-dithiolan-S,S-dioxid 
• 102861-91-6 1-(2,2-Diphenyl-1-thioxoethyl)pyrrolidin 
• 54191-80-9 N,N-dimethyl-2,2-diphenylthioacetamide 

Relevant articles and documents

Thioketene Syntheses, VIII. - Thioketenes by Cycloreversion of 1,3-Dithiolane Derivatives

2-Alkylidene-1,3-dithiolanes are transformed into S,S-dioxides 1 and S-ethyl- 2 or S-arylsulfonium salts 3.After deprotonation at C-5 they form in a cycloreversion thioketenes 5, which can be trapped as thioamides 17, 18.The stabilized thioketenes 5e,i-k afford 1:1 cycloadducts 24a, b, 27a-d with azomethines; in addition, thioketene 5j provides a dimer 28j, which was characterized by an X-ray structural investigation.