67961-02-8

Basic information

• Product Name: 6-ethyl-3-phenylcyclohex-2-enone
• Synonyms: 6-ethyl-3-phenylcyclohex-2-enone
• CAS NO: 67961-02-8
• Molecular Weight: 200.28
• Mol File: 67961-02-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-ethyl-3-phenylcyclohex-2-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 6-ethyl-3-phenylcyclohex-2-enone(67961-02-8)
• EPA Substance Registry System: 6-ethyl-3-phenylcyclohex-2-enone(67961-02-8)

Safety Data

• Hazardous Substances Data: 67961-02-8(Hazardous Substances Data)

Upstream product

• 879-72-1 3-(dimethylamino)propiophenone hydrochloride 
• 607-97-6 ethyl 2-ethyl-3-oxobutanoate 

Relevant articles and documents

Copper/Selectfluor-System-Catalyzed Dehydration-Oxidation of Tertiary Cycloalcohols: Access to β-Substituted Cyclohex-2-enones, 4-Arylcoumarins, and Biaryls

A route to β-substituted cyclohex-2-enones, 4-arylcoumarins, and biaryls has been developed. This approach involves a one-pot Cu0/Selectfluor-catalyzed dehydration-oxidation of tertiary cycloalcohols. Thus, by using 2 equiv. of Selectfluor at 25 C, the dehydration-oxidation of tertiary cyclohexanols and oxabenzocyclohexanols gave β-substituted cyclohex-2-enones and 4-arylcoumarins, respectively; whereas the dehydration-oxidation of tertiary cyclohexanols gave biaryls as the final products by using 2.5 equiv. of Selectfluor at 80 C. A route to β-substituted cyclohex-2-enones, 4-arylcoumarins, and biaryls has been developed. This approach involves a one-pot Cu0/Selectfluor-catalyzed dehydration-oxidation of tertiary cycloalcohols.