67964-39-0Relevant academic research and scientific papers
1,4-hydroiodination of dienyl alcohols with tmsi to form homoallylic alcohols containing a multisubstituted Z -alkene and application to prins cyclization
Xu, Yongjin,Yin, Zhiping,Lin, Xinglong,Gan, Zubao,He, Yanyang,Gao, Lu,Song, Zhenlei
supporting information, p. 1846 - 1849 (2015/04/27)
A regioselective 1,4-hydroiodination of dienyl alcohols has been developed using trimethylsilyl iodide as Lewis acid and iodide source. A range of homoallylic alcohols containing a multisubstituted Z-alkene was synthesized with good to excellent configurational control. The approach was applied in sequential hydroiodination/Prins cyclization to afford multisubstituted tetrahydropyrans diastereoselectively.
One-pot synthesis of substituted styrenes from vicinal dibromoalkanes and arylboronic acids
Tikhonov,Vasil'ev,Chirskaya,Struchkova,Merkulova,Zlotin
, p. 122 - 129 (2008/02/08)
Dehydrobromination of vicinal dibromoalkanes in systems comprising 1,2-dimethoxy-ethane, N-butyl-N′-methylimidazolium tetrafluoroborate (or tetrabutylammonium bromide), and a base with subsequent palladium-catalyzed cross-coupling of the thus formed bromoalkenes with arylboronic acids furnished substituted styrenes. Springer Science+Business Media, Inc. 2007.
