67977-95-1Relevant articles and documents
Preparation method of methylthiazoline
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Paragraph 0036; 0061; 0063-0067, (2020/11/12)
The invention provides a preparation method of methylthiazoline. According to the method, a one-pot-process low-temperature acylation esterification oxidation technology, an organic base catalysis chiral conversion technology, a desulfurization ring-opening synthesis technology, a comprehensive cyclic solvent utilization technology and a byproduct recycling technology are integrated, and the method is mature in technology, simple in synthesis process, few in reaction steps and low in raw material consumption and has the characteristics of good atom economy, good product quality and low cost.
2,4,6-TRIPYRIDINIO-1,3,5-TRIAZINE TRICHLORIDE, A NEW AND MILD ESTERIFICATION AGENT FOR PREPARATION OF PENICILLIN ESTERS
Murakami, Masayuki,Hajima, Makoto,Takami, Fumitaka,Yoshioka, Mitsuru
, p. 2055 - 2064 (2007/10/02)
Cyanuric chloride reacted with 3-molar equivalents of pyridine to give 2,4,6-tripyridinio-1,3,5-triazine trichloride, which was found to condense penicilins with alcohols under mild conditions to afford penicillin esters in good yields.Application to prep