679788-47-7

Upstream product

• 1663-39-4 tert-Butyl acrylate 
• 679788-46-6 (3S,3aS,7aR)-6-(2'-bromo-4'-methoxycyclohex-1'-enyl)-3-tert-butoxy-3a-methyl-2,3,3a,4,5,7a-hexahydro-1H-indene 
• 943589-84-2 1,4-dimethoxycyclohexene 
• 928758-66-1 (+)-(3S,3aS,7aR)-3-tert-butoxy-3a-methyl-2,3,3a,4,5,7a-hexahydro-1H-inden-6-yl trifluoromethanesulfonate 
• 654667-51-3 2-bromo-4-methoxy-1-trifluoromethanesulfonyloxycyclohexene 
• 69125-55-9 4-hydroxy-1-methoxy-1-cyclohexene 
• 41878-38-0 (1S,7aS)-1-tert-butoxy-7a-methyl-1,2,3,6,7,7a-hexahydro-5H-inden-5-one 
• 156497-38-0 (1S,3aR,7aS)-(1-tert-butoxy-7a-methyl-2,3,3a,6,7,7a-hexahydro-1H-inden-5-yloxy)trimethylsilane 
• 150-76-5 4-methoxy-phenol 
• 943589-85-3 2-bromo-4-methoxycyclohexanone 

Relevant academic research and scientific papers

Steroids and steroid analogues from Stille-Heck coupling sequences

Tricyclic 1,3,5-hexatrienes were prepared from 4-substituted 2-bromocyclohexenyl triflate, enantiomerically pure hexahydroindenylstannanes, and tert-butyl acrylate in a sequence of Stille and Heck reactions. In the example shown, an enantiomerically pure

Stille-heck coupling sequences applied in a versatile new access to steroid skeletons

A variety of enantiomerically pure steroidal compounds was synthesized utilizing a sequence of Stille and Heck cross-coupling reactions and subsequent thermal 6π-electrocyclizations. Highly chemoselective Stille couplings on the triflate moiety of several