679813-29-7Relevant academic research and scientific papers
Nucleophilic epoxidation of γ-alkoxy dienyl sulfoxide derivatives
Fernández De La Pradilla, Roberto,Victoria Buergo, María,Montero, Carlos,Viso, Alma
, p. 2684 - 2692 (2007/10/03)
(E,E) and (Z,E) γ-alkoxy dienyl sulfones undergo nucleophilic epoxidation with remarkable regio- and stereoselectivity to render syn oxiranes in a process mainly controlled by the alkoxy stereocenter. Upon epoxidation γ-hydroxy dienyl sulfoxides provide s
Sulfur-Directed Synthesis of Enantiopure Hydroxy 2-Sulfinyl Butadienes
Fernandez De La Pradilla, Roberto,Buergo, Maria Victoria,Martinez, Maria Victoria,Montero, Carlos,Tortosa, Mariola,Viso, Alma
, p. 1978 - 1986 (2007/10/03)
The treatment of sulfinyl chlorohydrins with KO-t-Bu in THF generates epoxy vinyl sulfoxides that undergo an efficient base-induced rearrangement to generate enantiopure hydroxy 2-sulfinyl dienes. This novel process takes place with high chemo- and stereo
