679813-40-2Relevant academic research and scientific papers
Sulfur-Directed Synthesis of Enantiopure Hydroxy 2-Sulfinyl Butadienes
Fernandez De La Pradilla, Roberto,Buergo, Maria Victoria,Martinez, Maria Victoria,Montero, Carlos,Tortosa, Mariola,Viso, Alma
, p. 1978 - 1986 (2007/10/03)
The treatment of sulfinyl chlorohydrins with KO-t-Bu in THF generates epoxy vinyl sulfoxides that undergo an efficient base-induced rearrangement to generate enantiopure hydroxy 2-sulfinyl dienes. This novel process takes place with high chemo- and stereo
