68014-58-4

Basic information

• Product Name: N-Mesityl-2,6-dimethylaniline
• Synonyms: N-Mesityl-2,6-dimethylaniline;2,6-Dimethyl-N-(2,4,6-trimethylphenyl)benzenamine
• CAS NO: 68014-58-4
• Molecular Formula: C₁₇H₂₁N
• Molecular Weight: 239.36
• Mol File: 68014-58-4.mol
• Article Data: 24

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-Mesityl-2,6-dimethylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-Mesityl-2,6-dimethylaniline(68014-58-4)
• EPA Substance Registry System: N-Mesityl-2,6-dimethylaniline(68014-58-4)

Safety Data

• Hazardous Substances Data: 68014-58-4(Hazardous Substances Data)

Upstream product

• 6781-98-2 2,6-dimethyl-1-chlorobenzene 
• 88-05-1 2,4,6-trimethylaniline 
• 1667-04-5 2-bromomesitylene 
• 87-62-7 2,6-dimethylaniline 
• 608-28-6 2,6-dimethyliodobenzene 
• 576-22-7 2-Bromo-m-xylene 
• 576-83-0 2,4,6-trimethylphenyl bromide 

Relevant articles and documents

Synthesis of N-heterocyclic carbene-Pd(II)-5-phenyloxazole complexes and initial studies of their catalytic activity toward the Buchwald-Hartwig amination of aryl chlorides

Three new N-heterocyclic carbene (NHC)-Pd(II) complexes using 5-phenyloxazole as the ancillary ligand have been obtained in moderate to good yields by a one-pot reaction of the corresponding imidazolium salts, palladium chloride and 5-phenyloxazole under mild conditions. Initial studies showed that one of the complexes is an efficient catalyst for the Buchwald-Hartwig amination of aryl chlorides with various secondary and primary amines under the varied catalyst loading of 0.01-0.05 mol%, thus it will enrich the chemistry of NHCs and give an alternative catalyst for the coupling of challenging while cost-low aryl chlorides.

Sterically Hindered Amination of Aryl Chlorides Catalyzed by a New Carbazolyl-Derived P,N-Ligand-Composed Palladium Complex

A family of 2-(9 H -carbazol-9-yl)phenyl-based phosphine ligands were synthesized and their efficacy in promoting the steric hindered Buchwald-Hartwig amination was evaluated. In the presence of Pd(OAc) 2 (0.03-1.0 molpercent) associated with t

N-Heterocyclic carbene-palladacyclic complexes: synthesis, characterization and their applications in the C-N coupling and α-arylation of ketones using aryl chlorides

N-Heterocyclic carbene-palladacyclic complexes 3 were successfully achieved in a one-pot procedure under mild conditions. The structure of 3a was unambiguously confirmed by X-ray single crystal diffraction and it was an active catalyst in the Buchwald-Hartwig amination and α-arylation of ketones even at very low catalyst loadings (0.01 mol%).