68039-70-3Relevant articles and documents
Direct copper-free domino conjugate addition-cycloallylation using organozinc reagents
Komanduri, Venukrishnan,Pedraza, Fernando,Krische, Michael J.
, p. 1569 - 1576 (2008)
The Direct Approach: Enones possessing appendant allylic carbonates react directly with diorganozinc reagents in the presence of zinc diiodide [ZnI 2] to provide 5- and 6-membered ring products of tandem or domino conjugate addition-cycloallylation in good to excellent yield. In a related copper-free transformation, allylic carbonates are found to engage in direct allylic substitution with diorganozinc reagents.