68058-02-6Relevant academic research and scientific papers
A novel copper framework with amino tridentate N-donor ligand as heterogeneous catalyst for ring opening of epoxides
Huang, Zi-Qing,Xu, Zou-Hong,Liu, Xiao-Hui,Zhao, Yue,Wang, Peng,Liu, Zhi-Qiang,Sun, Wei-Yin
, (2021/04/22)
A novel metal–organic framework (MOF) [Cu3L(2,6-NDC)2]·0.5DMF (MOF-Cu-1) was synthesized by solvothermal reaction of copper nitrate trihydrate with 2,6-naphthalenedicarboxylic acid (2,6-H2NDC) and amino tridentate N-donor
Inexpensive Reagents for the Synthesis of Amides from Esters and for Regioselective Opening of Epoxides
Solladie-Cavallo, A.,Bencheqroun, M.
, p. 5831 - 5834 (2007/10/02)
Lithium aluminum amides , 6a-6d, easily prepared in Et2O or THF from 1 equiv of LiAlH4 and 5 equiv of amine, proved to be efficient reagents for the synthesis of secondary amides from esters (ca. 100 percent with unhindered amines and 92 percent with t-BuNH2).They also open aryl epoxides with very high regioselectivity to give 97-98 percent of the β-amino-α-arylethanols (corresponding to the SN2 mechanism).
Synthesis of 2,2-Dichloro-1,3-diarylaziridines by Reduction of Trichloroacetophenone Imines
Kimpe, Norbert De,Verhe, Roland,Buyck, Laurent De,Schamp, Niceas
, p. 2079 - 2081 (2007/10/02)
2,2-Dichloro-1,3-diarylaziridines, usually obtained by addition of dichlorocarbene to benzylideneanilines, were synthesized by reaction of N-aryl-α,α,α-trichloroacetophenone imines with lithium aluminium hydride in ether.
