680580-77-2Relevant academic research and scientific papers
Synthesis and Reactivity of Ortho-Mercuriated and Orthio-Palladated Arylacetals and Cyclic and Acyclic Aryldithioacetals. New Examples of the Rearrangement of Acyclic Dithioacetal Aryl- to Dithioether Alkyl-Palladium Complexes
Vicente, Jose,Abad, Jose-Antonio,Hernandez-Mata, Francisco S.,Rink, Barbara,Jones, Peter G.,Ramirez de Arellano, M. Carmen
, p. 1292 - 1304 (2004)
The synthesis of ortho-palladated complexes by transmetalation reactions was studied using arylmercurials, by oxidative additions of the haloarenes to palladium(0) species. Orthopalladated amines or imines were synthesized by reacting them with palladium acetate. The reactions with isocyanides giving complexes were studied resulting after mono or tri-insertion. The greater trans influence of the aryl with respect to the chloro ligand caused the Pd-N(2) distance to be longer than the PdN(1) bond length.
