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(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

680592-40-9

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680592-40-9 Usage

Reaction

Reagent used in the enantioselective Friedel-Crafts alkylations with benzoylhydrazones. Reagent used in highly enantioselective [3+2] acylhydrazone-enol ether cycloadditions.

Check Digit Verification of cas no

The CAS Registry Mumber 680592-40-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 6,8,0,5,9 and 2 respectively; the second part has 2 digits, 4 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 680592-40:
(8*6)+(7*8)+(6*0)+(5*5)+(4*9)+(3*2)+(2*4)+(1*0)=179
179 % 10 = 9
So 680592-40-9 is a valid CAS Registry Number.

680592-40-9 Well-known Company Product Price

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  • (Code)Product description
  • CAS number
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  • Aldrich

  • (720380)  (4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane  97%

  • 680592-40-9

  • 720380-1G

  • 333.45CNY

  • Detail

  • Aldrich

  • (720380)  (4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane  97%

  • 680592-40-9

  • 720380-5G

  • 1,340.82CNY

  • Detail

680592-40-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name (2S,4S)-2-chloro-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazasilolidine

1.2 Other means of identification

Product number -
Other names (S,S)-2-PHENYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:680592-40-9 SDS

680592-40-9Downstream Products

680592-40-9Relevant academic research and scientific papers

SILACYCLE COMPOUNDS AND METHODS OF USE THEREOF

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Page/Page column 24; 25, (2010/11/08)

The present invention relates to a diastereomeric mixture of Silacycle Compounds and methods for using the diastereomeric mixture of Silacycle Compounds for stereoselective synthesis.

Enantioselective friedel-crafts alkylations with benzoylhydrazones promoted by a simple strained silacycle reagent

Shirakawa, Seiji,Berger, Richard,Leighton, James L.

, p. 2858 - 2859 (2007/10/03)

The enantioselective Friedel-Crafts reaction of electron-rich arenes and heteroarenes with the benzoylhydrazone of isopropyl glyoxylate mediated by a simple chiral silane Lewis acid is described. The reactions are highly practical, as demonstrated by a la

Enantioselective Allylation of Ketone-Derived Benzoylhydrazones: Practical Synthesis of Tertiary Carbinamines

Berger, Richard,Duff, Keiko,Leighton, James L.

, p. 5686 - 5687 (2007/10/03)

A highly practical method for the enantioselective allylation of ketone-derived benzoylhydrazones has been developed. The previously reported strained silacycle reagent 1 reacts with a wide variety of benzoylhydrazones to give the hydrazide products with

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