68080-88-6

Basic information

• Product Name: 1-(3,4-dimethoxybenzyl)-6,7-dimethoxyisochromane
• Synonyms: 1-(3,4-dimethoxybenzyl)-6,7-dimethoxyisochromane
• CAS NO: 68080-88-6
• Molecular Weight: 344.408
• Mol File: 68080-88-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(3,4-dimethoxybenzyl)-6,7-dimethoxyisochromane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3,4-dimethoxybenzyl)-6,7-dimethoxyisochromane(68080-88-6)
• EPA Substance Registry System: 1-(3,4-dimethoxybenzyl)-6,7-dimethoxyisochromane(68080-88-6)

Safety Data

• Hazardous Substances Data: 68080-88-6(Hazardous Substances Data)

Upstream product

• 159730-37-7 1-(3,4-dimethoxyphenyl)-2-methoxyethylene 
• 7417-21-2 2-(3,4-dimethoxyphenyl)ethyl alcohol 
• 122752-81-2 2-(3,4-dimethoxyphenyl)-1-<2-(2-hydroxyethyl)-4,5-dimethoxyphenyl>ethanol 
• 26954-85-8 o-homoveratroylhomoveratric acid 

Relevant articles and documents

Synthesis and Acid-Catalyzed Cyclization of 2-Alkenylstilbenes: A New Approach to the Substituted Indenes

A base-catalyzed ring-opening of 1-benzylisochromans 1 firstly produced 2-alkenylstilbenes 2, which then underwent a mild acid-catalyzed intramolecular cyclization to furnish 1,2-disubstituted indenes 3 in high yields. Subsequently, a base-catalyzed isomerization of the 1,2-disubstituted indenes 3 afforded the more stable 2,3-disubstituted indenes 4 in almost quantitative yields.

OXIDATION OF 2-ETHANOL USING CHROMIUM (VI) REAGENTS

The oxidation reaction of the title compound by means of chromium (VI) reagents afforded, not the expected dicarbonyl derivative, but cyclization compounds.Their structures determined on the basis of their spectral data are reported.