681006-05-3Relevant academic research and scientific papers
Nucleophilic synthesis of enantiopure 2-(tributylstannyl)pyrrolidines and piperidines
Gawley, Robert E.,Barolli, Graciela,Madan, Sachin,Saverin, Michele,O'Connor, Sean
, p. 1759 - 1761 (2007/10/03)
trans-Cumylcyclohexanol (TCC) is used as a chiral auxiliary for the stereoselective addition of tributyltinlithium to N-acylpyrrolidinium/ piperidinium ion with 70-80% diastereoselectivity at 0°C. After removal of the minor diastereomer by radial chromato
