681035-94-9

Basic information

• Product Name: Benzene, 2-methoxy-1-methyl-4-(trifluoromethyl)- (9CI)
• Synonyms: Benzene, 2-methoxy-1-methyl-4-(trifluoromethyl)- (9CI);2-METHYL-5-(TRIFLUOROMETHYL)ANISOLE
• CAS NO: 681035-94-9
• Molecular Formula: C9H9F3O
• Molecular Weight: 190.1623696
• Product Categories: METHOXY
• Mol File: 681035-94-9.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 180.8±40.0 °C(Predicted)
• Appearance: /
• Density: 1.165±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzene, 2-methoxy-1-methyl-4-(trifluoromethyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 2-methoxy-1-methyl-4-(trifluoromethyl)- (9CI)(681035-94-9)
• EPA Substance Registry System: Benzene, 2-methoxy-1-methyl-4-(trifluoromethyl)- (9CI)(681035-94-9)

Safety Data

• Hazardous Substances Data: 681035-94-9(Hazardous Substances Data)

Relevant articles and documents

Trifluoromethylated Vinylic and Aromatic Compounds from α-(Trifluoromethyl)allyl Alcohols

α-(Trifluoromethyl)allyl alcohols, easily available from α,β-unsaturated carbonyl compounds, are readily converted into γ-(trifluoromethyl)allyl thioethers, benzyl ethers, trifluoroacetates, and azides. A phenyl substituent at the γ-position to the hydroxyl function enhances their reactivity and the ease of SN2′ or SN1′ substitutions, whereas a phenyl ring at the α-position allows the BF3-mediated synthesis of (trifluoromethyl)indenes. 4-Alkyl-4-methoxy-1-(trifluoromethyl)cyclohexa-2,5- dienols, readily available from 4-alkylphenols, are easily converted to 4-alkyl(trifluoromethyl)benzenes bearing a nucleophilic substituent (MeO, Cl) either on the ring or the benzylic position.