681449-41-2

Upstream product

• 681449-39-8 (1S,2R,3R,4R)-2-(tert-butyldiphenylsilyloxymethyl)-1,4-bis-O-(triethylsilyl)-3-(2-hydroxyethyl)cyclopentane-1,4-diol 
• 213777-18-5 (1S,2S,3R,4R)-1,4-Bis(triethylsilyloxy)-3-(methoxycarbonylmethyl)-2-tert-butyldiphenylsilyloxymethylcyclopentane 
• 681449-40-1 (1S,2R,3R,4R)-2-(tert-butyldiphenylsilyloxymethyl)-1,4-bis-O-(triethylsilyl)-3-[2-(4-methylbenzenesulfonyloxy)ethyl]cyclopentane-1,4-diol 

Downstream Products

• 681449-42-3 (1S,2R,3R,4R)-2-(tert-butyldiphenylsilyloxymethyl)-3-ethylcyclopentane-1,4-diol 
• 681449-45-6 C₂₂H₂₂O₅ 
• 681449-44-5 (1S,2R,3R,4R)-1,4-di-O-benzoyl-3-ethylcyclopentane-1,4-diol 
• 681449-43-4 (1S,2R,3R,4R)-1,4-di-O-benzoyl-2-(tert-butyldiphenylsilyloxymethyl)-3-ethylcyclopentane-1,4-diol 
• 681449-48-9 (1S,2S,3R,4R)-1,4-di-O-benzoyl-3-ethyl-2-[(1E,3R)-10-(ethoxycarbonyl)-3-hydroxydec-1-enyl]cyclopentane-1,4-diol 
• 681449-49-0 (1S,2S,3R,4R)-1,4-di-O-benzoyl-3-ethyl-2-[(1E,3S)-10-(ethoxycarbonyl)-3-hydroxydec-1-enyl]cyclopentane-1,4-diol 
• 681449-46-7 (1S,2S,3R,4R)-1,4-di-O-benzoyl-3-ethyl-2-[(E)-10-(ethoxycarbonyl)-3-oxodec-1-enyl]cyclopentane-1,4-diol 

Relevant academic research and scientific papers

Total Synthesis of the Eight Diastereomers of the Syn-Anti-Syn Phytoprostanes F1 Types I and II

Syntheses of the eight enantiomerically pure diastereomers of the syn-anti-syn phytoprostanes F1 types I and II are described starting from D- and L-glucose. Key steps include Wittig coupling, Horner Wadsworth Emmons (HWE) reactions, and enantioselective reduction of α,β -unsaturated ketones.