68211-39-2Relevant academic research and scientific papers
Torsional, rotor, and electronic effects in 4-tert-butylmethylenecyclohexane epoxidations and osmylations
Vedejs,Dent III,Kendall,Oliver
, p. 3556 - 3567 (2007/10/03)
The axial epoxidation preference for 2-substituted 4-tert-butylmethylenecyclohexanes is attributed to a combination of small effects, including existing bond torsion and rotor effects. Contributions from developing bond torsion are smaller and may be negl
The conformational preference of methoxyl and acetoxyl groups in 3-oxycyclohexenes, 2-oxymethylenecyclohexanes, and 1-oxytetralins and the generalized anomeric effect
Ouedraogo, Adama,Viet, Minh Tan Phan,Saunders, John K.,Lessard, Jean
, p. 1761 - 1768 (2007/10/02)
The 13C and 1H nuclear magnetic resonance data of 3-oxycyclohexenes, 2-oxymethylenecyclohexanes, and 1-oxytetralins show (i) that the pseudoaxial preference is larger for the acetoxyl group than for the methoxyl group in 3-oxycyclohexenes, (ii) that the m
