68211-44-9

Basic information

• Product Name: 4A-(2H)-Naphthalenol, 1,3,4,7,8,8A-hexahydro-8A-methyl-, cis-
• Synonyms: 4A-(2H)-Naphthalenol, 1,3,4,7,8,8A-hexahydro-8A-methyl-, cis-
• CAS NO: 68211-44-9
• Molecular Formula: C₁₁H₁₈O
• Molecular Weight: 166.26002
• Mol File: 68211-44-9.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 243°Cat760mmHg
• Flash Point: 96.6°C
• Appearance: /
• Density: 1.05g/cm³
• Vapor Pressure: 0.00558mmHg at 25°C
• Refractive Index: 1.543
• CAS DataBase Reference: 4A-(2H)-Naphthalenol, 1,3,4,7,8,8A-hexahydro-8A-methyl-, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: 4A-(2H)-Naphthalenol, 1,3,4,7,8,8A-hexahydro-8A-methyl-, cis-(68211-44-9)
• EPA Substance Registry System: 4A-(2H)-Naphthalenol, 1,3,4,7,8,8A-hexahydro-8A-methyl-, cis-(68211-44-9)

Safety Data

• Hazardous Substances Data: 68211-44-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H18O/c1-10-6-2-4-8-11(10,12)9-5-3-7-10/h4,8,12H,2-3,5-7,9H2,1H3

Upstream product

• 13943-77-6 10-methyl-Δ^1,9-octalin 
• 120236-53-5 8aβ-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-4aβ-yl hydroperoxide 

Downstream Products

• 76402-81-8 6-(4-Iodo-butyl)-6-methyl-cyclohex-2-enone 
• 5173-74-0 cis-6-methylbicyclo<4.3.0>decan-1-ol 

Relevant articles and documents

Stereoselectivity in the Formation and Allylic Rearrangement of 8a-Methyl- and 8a-Ethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalenyl Hydroperoxides

4a-Methyl- and 4a-ethyl-1,2,3,4,4a,5,6,7-octahydronaphthalene have been subjected to singlet oxygen oxygenation, and the various hydroperoxides which are formed have been characterised.Evidence is presented that the 8aβ-alkyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-4aα-yl hydroperoxides (I; R=Me or Et) rearrange suprafacially and irreversibly in chloroform at 25 deg C to give only the 4aβ-alkyl-2,3,4,4a,5,6,7,8-octahydronaphthalen-2α-yl hydroperoxides (II).Under the same conditions, the corresponding 8aβ-alkyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-4aβ-yl hydroperoxides rearrange much more slowly.