682339-15-7Relevant articles and documents
Copper-Catalyzed SN2′-Selective Allylic Substitution Reaction of gem-Diborylalkanes
Zhang, Zhen-Qi,Zhang, Ben,Lu, Xi,Liu, Jing-Hui,Lu, Xiao-Yu,Xiao, Bin,Fu, Yao
, p. 952 - 955 (2016)
A Cu/(NHC)-catalyzed SN2′-selective substitution reaction of allylic electrophiles with gem-diborylalkanes is reported. Different substituted gem-diborylalkanes and allylic electrophiles can be employed in this reaction, and various synthetic valuable functional groups can be tolerated. The asymmetric version of this reaction was initially researched with chiral N-heterocyclic carbene (NHC) ligands.