682350-75-0Relevant academic research and scientific papers
Syntheses of (Z)-allyl chlorides from Baylis-Hillman adducts with a trichlorotriazine/DMF system
Li, Jian,Li, Shaoyu,Jia, Xueshun,Zhang, Yongmin
, p. 48 - 49 (2008/09/20)
Stereoselective transformation of Baylis-Hillman adducts 1 into corresponding (2)-allyl chlorides 2 have been achieved by treatment with 2,4,6-trichloro [1,3,5]triazine and N, N-dimethyl formamide. This novel approach proceeds readily at room temperature
A simple and efficient protocol for chlorination of baylis-hillman adducts using PPh3/CCl4
Das, Biswanath,Kanth, Boddu Shashi,Reddy, Kongara Ravinder,Satyalakshmi, Gandham,Kumar, Rathod Aravind
, p. 512 - 513 (2008/09/21)
PPh3/CCl4 system has been employed for the stereoselective synthesis of (Z)- and (E)-allyl chlorides from Baylis-Hillman adducts in excellent yields. Copyright
A mild and efficient method for chlorination of Baylis-Hillman adducts using PPh3/Cl3CCONH2
Das, Biswanath,Chowdhury, Nikhil,Damodar, Kongara,Ravikanth, Bommena
, p. 2037 - 2040 (2008/03/13)
A new and convenient stereoselective synthesis of (Z)-2-(chloromethyl)alk- 2-enoates has been achieved from Baylis - Hillman adducts by treatment with PPh3/Cl3CCONH2 at room temperature. The synthesis can proceed under mil
Expedient synthesis of β,β-disubstituted α- methylenepropionates
Biswas, Kallolmay,B?rner, Christoph,Gimeno, Josepe,Goldsmith, Paul J.,Ramazzotti, Daniella,So, Angela L.K.,Woodward, Simon
, p. 1433 - 1442 (2007/10/03)
Baylis-Hillman alcohols are excellent sources of the allylic halides ArCHCH(CH2X)(CO2R) (X=Br, Cl; R1=Me, Et, But). The Z double bond isomers are attained in high isomeric purity (>14:1, Z/E). The halides are ch
Convenient and efficient stereoselective synthesis of (2Z)-2-(chloromethyl) alk-2-enoates using iron(III) or indium(III) chloride
Das, Biswanath,Banerjee, Joydeep,Ravindranath, Nasi,Venkataiah, Bollu
, p. 2425 - 2426 (2007/10/03)
The stereoselective synthesis of (2Z)-2-(chloromethyl)alk-2-enoates has been achieved efficiently and in high yields and in short reaction times from Baylis-Hillman adducts, 3-hydroxy-2-methylene-alkanoates, by treatment with FeCl3 or InCl
