682356-27-0

Basic information

• Product Name: 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[3-(1-methylcyclohexyl)-1-propynyl]-
• CAS NO: 682356-27-0
• Molecular Formula: C16H27BO2
• Molecular Weight: 262.2
• Mol File: 682356-27-0.mol

Chemical Properties

• CAS DataBase Reference: 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[3-(1-methylcyclohexyl)-1-propynyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[3-(1-methylcyclohexyl)-1-propynyl]-(682356-27-0)
• EPA Substance Registry System: 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[3-(1-methylcyclohexyl)-1-propynyl]-(682356-27-0)

Safety Data

• Hazardous Substances Data: 682356-27-0(Hazardous Substances Data)

Upstream product

• 61676-62-8 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 682356-26-9 1-(3,3-dibromo-allyl)-1-methyl-cyclohexane 
• 79405-31-5 (1-methylcyclohexyl)acetaldehyde 

Downstream Products

• 682356-28-1 2-(1-methylcyclohexylmethyl)-3-(4,4,5,5-tetramethyl-[1,3,2]-dioxaborolan-2-yl)dibenzofuran-1,4-dione 
• 682356-34-9 7-(t-butyldiphenylsilyloxy)-2-(1-methylcyclohexylmethyl)-3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)dibenzofuran-1,4-dione 

Relevant articles and documents

Stereoselective electrogeneration of (E)-4-alkoxy-2-phenyl-5-chloro-2- oxazolines by cathodic reduction of N-(1-alkoxy-2,2,2-trichloroethyl)benzamides

The first method for the synthesis of the title compounds has been established. Quantitative reactions of benzamides with chloral hydrate provided chloralbenzamides which were efficiently converted to N-(1,2,2,2- tetrachloroethyl)amides by treatment with

Synthesis of dibenzofuran-1,4-diones using the D?tz benzannulation

The chromium Fischer carbene complexes of benzofuran and benzothiophene have been prepared and can be used in D?tz benzannulations with alkynes for the regioselective and converg ent synthesis of dibenzofuran-1,4-dione heterocycles. The use of alkynylboronates led to model systems of the tricyclic ring system of popolohuanone E after oxidation. It would appear that the combination of alkynyl boronates with furan type Fischer carbene complexes leads to substantial amounts (～50%) of protodeboronated products.