68240-79-9Relevant articles and documents
SN1 reactions with inverse rate profiles
Denegri, Bernard,Minegishi, Shinya,Kronja, Olga,Mayr, Herbert
, p. 2302 - 2305 (2004)
Carbocations may accumulate during solvolysis reactions! The fact that fast ionization followed by slow trapping of the carbocation R+ is a characteristic pattern of many solvolysis reactions requires that the generally accepted energy profiles of these reactions be revised.